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Enantioselective intermolecular free radical conjugate additions. Application of a pyrazole template

✍ Scribed by Mukund P. Sibi; John J. Shay; Jianguo Ji

Book ID: 104257705
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 207 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01353-1

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✦ Synopsis

An achiral pyrazole template has been evaluated in enantioselective conjugate radical additions. The enantioselectivity using the pyrazole template is inferior to those obtained from an oxazolidinone template. The two templates give products of opposite configuration using the same chiral Lewis acid.

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