Enantioselective Hydrogen Transfer from a Chiral Tin Hydride to a Prochiral Carbon-Centered Radical

Enantioselectivity of the Transfer of Hy

Enantioselectivity of the Transfer of Hydrogen Atoms to Acyclic Prochiral Carbon-Centred Radicals Using Chiral Tin Hydrides

✍ Kay Schwarzkopf; Michael Blumenstein; Ahlke Hayen; Jürgen O. Metzger 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 441 KB 👁 2 views

Racemic α-bromo esters 2 have been reduced via prochiral that the minor diastereomer of tin hydrides 1a and 1b reacts with good enantioselectivity whereas the major diastereomer radicals 5 with low to moderate enantioselectivities using chiral tin hydrides 1 with a stereogenic tin atom containing re