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Enantioselective Guest Binding and Dynamic Resolution of Cationic Ruthenium Complexes by a Chiral Metal−Ligand Assembly

✍ Scribed by Fiedler, Dorothea; Leung, Dennis H.; Bergman, Robert G.; Raymond, Kenneth N.


Book ID
124102423
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
69 KB
Volume
126
Category
Article
ISSN
0002-7863

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The structures of (R,S)-and (RR)-(saJen)manganese(III) complexes [(R,S)-2a,b and (R,R)-2a,b] possessing axial chirality as one of their two chiral elements were unambiguously determined by X-ray crystallographic analysis. The basal salen ligands of the complexes were demonstrated to adopt a stepped