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Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

✍ Scribed by Briones, John F.; Davies, Huw M. L.


Book ID
120926809
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
325 KB
Volume
135
Category
Article
ISSN
0002-7863

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Formal [4+2] cycloaddition between 3-eth
✍ Jun-ichi Matsuo; Shoko Negishi; Hiroyuki Ishibashi πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 308 KB

3-Ethoxycyclobutanones reacted with silyl enol ethers to give formal [4+2] cycloadducts, 3-ethoxy-5trimethylsiloxycyclohexanone derivatives, by using ethylaluminum dichloride as a Lewis acid. Highly oxygenated cyclohexanone derivatives were stereoselectively prepared by this method.