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Enantioselective epoxidation of tertiary allylic alcohols by chiral dihydroperoxides

✍ Scribed by Bunge, Alexander; Hamann, Hans-Jürgen; Dietz, Dennis; Liebscher, Jürgen

Book ID
120057117
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
289 KB
Volume
69
Category
Article
ISSN
0040-4020

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Asymmetric epoxidation of chiral allylic
Asymmetric epoxidation of chiral allylic alcohols
✍ Erwin G.J.C. Warmerdam; Adrianus M.C.H. van den Nieuwendijk; Johannes Brussee; C 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 654 KB

Two series of chiral allylic alcohols, derived from c~,~-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several threo and