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Enantioselective Diels−Alder Reactions of Optically Active (Buta-1,3-dien-2-yl)(salen)cobalt(III) Complexes

✍ Scribed by John J. Chapman; Cynthia S. Day; Mark E. Welker

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
452 KB
Volume
2001
Category
Article
ISSN
1434-193X

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## Abstract The reaction of alkenes (VI) with chiral hypervalent iodine reagent in the presence of acetic acid and the subsequent acetylation of the resulting regioisomeric mixture of monoacetylated products affords desired syn‐diacetates (VII) with high diastereo‐ and enantioselectivities.