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Enantioselective deoxygenation of alkyl aryl sulfoxides by DMSO reductase from Rhodobacter sphaeroides f.s. denitrificans

โœ Scribed by Mitsuru Abo; Makoto Tachibana; Akira Okubo; Sunao Yamazaki


Book ID
103992076
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
283 KB
Volume
3
Category
Article
ISSN
0968-0896

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Preparative asymmetric deoxygenation of
โœ Mitsuru Abo; Akira Okubo; Sunao Yamazaki ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 222 KB

Preparative enantioselective deoxygenation of racemic alkyl aryl sulfoxides by intact cells of Rhodobacter sphaeroides f.sp. denitrificans was examined. In methyl p-substituted phenyl sulfoxides, (S)-enantiomers were exclusively deoxygenated while enantiomerically pure (R)-isomers were recovered in