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Enantioselective decomposition of chiral alkyl bromides on Cu(6 4 3)R&S: Effects of moving the chiral center

✍ Scribed by D.M. Rampulla; A.J. Gellman


Book ID
108279348
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
220 KB
Volume
600
Category
Article
ISSN
0039-6028

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Regio- and enantioselectivity in the alk
✍ Maria Saporita; Giovanni Bottari; Giuseppe Bruno; Dario Drommi; Felice Faraone πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 206 KB

a b s t r a c t [( 5 -C 5 R 5 )Ru(N-N\*)(NCMe)]PF 6 (R = H, N-N\* = (Sa)-1, 5; (Sa)-2, 6; (R,R)-3, 7; (R,R)-4; 8; R = Me, N-N\* = (Sa)-1, 9) complexes containing N-N\* bulky chiral ligands of different rigidity and flexibility were synthesized by reacting the precursor [( 5 -C 5 R 5 )Ru(NCMe) 3 ]PF