Regio- and enantioselectivity in the alk
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Maria Saporita; Giovanni Bottari; Giuseppe Bruno; Dario Drommi; Felice Faraone
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Article
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2009
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Elsevier Science
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English
β 206 KB
a b s t r a c t [( 5 -C 5 R 5 )Ru(N-N\*)(NCMe)]PF 6 (R = H, N-N\* = (Sa)-1, 5; (Sa)-2, 6; (R,R)-3, 7; (R,R)-4; 8; R = Me, N-N\* = (Sa)-1, 9) complexes containing N-N\* bulky chiral ligands of different rigidity and flexibility were synthesized by reacting the precursor [( 5 -C 5 R 5 )Ru(NCMe) 3 ]PF