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Enantioselective Complexation of Flexible and Rigid Substrates through Molecular Recognition

โœ Scribed by Dr. Michael Famulok; Dr. Kyu-Sung Jeong; Dr. Ghislain Deslongchamps; Prof. Julius Rebek Jr.


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
347 KB
Volume
30
Category
Article
ISSN
0044-8249

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## Abstract The binaphthyl metallocleft 2 in which an electrophilic uranyl cation is immobilized was synthesized by reaction of 1,2โ€benzenediamine and aldehyde 5. According to ^1^Hโ€NMR spectroscopy, 2 is formed as a mixture of meso and racemic diastereomers (ratio 1:0.85). The complexation of 2 wit