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Enantioselective CH Amination Using Cationic Ruthenium(II)–pybox Catalysts

✍ Scribed by Erika Milczek; Nadège Boudet; Simon Blakey


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
319 KB
Volume
47
Category
Article
ISSN
0044-8249

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✍ Darío Cuervo; M. Pilar Gamasa; José Gimeno 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 2 views

Treatment of complex trans-[RuCl(2)(eta(2)-C(2)H(4))[kappa(3)-N,N,N-(R,R)-Ph-pybox]] [(R,R)-Ph-pybox = 2,6-bis[4'-(R)-phenyloxazolin-2'-yl]pyridine] with phosphines or phosphites in dichloromethane at 50 degrees C leads to the formation of novel ruthenium(II)-pybox complexes trans-[RuCl(2)(L)[kappa(

Bis(ortho)-Chelated Bis(phosphanyl)aryl