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Enantioselective Catalysis, 471 Rhodium(II)-Carboxylate Complexes and Their Use In the Enantioselective Cyclopropanation

โœ Scribed by H. Brunner; H. Kluschanzoff; K. Wutz


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
385 KB
Volume
98
Category
Article
ISSN
0037-9646

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ChemInform Abstract: Enantioselective Sy
โœ H. M. L. DAVIES; J. J. MATASI; L. M. HODGES; N. J. S. HUBY; C. THORNLEY; N. KONG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB

## Enantioselective Synthesis of Functionalized Tropanes by Rhodium(II) Carboxylate-Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Pyrroles. -A number of enantiomerically enriched tropones can be prepared efficiently using the title method. The reaction proceeds via a tandem cycl