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Enantioselective bis-alkoxycarbonylation of styrene catalyzed by novel chiral dipyridylphosphine cationic palladium(II) complexes

✍ Scribed by Lailai Wang; Waihim Kwok; Jing Wu; Rongwei Guo; Terry T.-L Au-Yeung; Zhongyuan Zhou; Albert S.C Chan; Kin-Shing Chan


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
141 KB
Volume
196
Category
Article
ISSN
1381-1169

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The conjugate addition of propionate silylketcne acetal 1 to 2-carbomethoxy cyclopentenone is promoted by bis(oxazoline)-Cu(ll) complexes with high diastcreosclectivity and good enantiomeric excesses. The absolute configuration of the product can bc controlled by varying the copper counterion. A ca