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Enantioselective Aziridination of Alkenes with N -Aminophthalimide in the Presence of Lead Tetraacetate-Mediated Chiral Ligand

✍ Scribed by Yang, Kung-Shou; Chen, Kwunmin


Book ID
118737828
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
51 KB
Volume
4
Category
Article
ISSN
1523-7060

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## Abstract The stereochemical course of the rearrangement of the __N__‐sulfonylaziridines **5, 15**, and **25** in the presence of __s__‐BuLi/(βˆ’)‐sparteine to the bicyclic sulfonamides **4, 16**, and **17**, respectively, has been investigated chemically and by X‐ray structure analysis. The absolu