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Enantioselective and Catalytic Method for α-Crotylation of Aldehydes with a Kinetic Self-Refinement of Stereochemistry

✍ Scribed by Andrei V. Malkov; Mikhail A. Kabeshov; Maciej Barłog; Pavel Kočovský

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
216 KB
Volume
15
Category
Article
ISSN
0947-6539

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An Efficient Enantioselective Method for Asymmetric Friedel–Crafts Alkylation of Indoles with α,β-Unsaturated Aldehydes
✍ Liang Hong; Lei Wang; Chao Chen; Bangzhi Zhang; Rui Wang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 2 views

## Abstract magnified image The Lewis base‐Lewis base bifunctional catalytic system has been developed and successfully applied to the asymmetric Friedel–Crafts alkylation of indoles with α,β‐unsaturated aldehydes. The reactions are promoted by chiral diphenylprolinol trimethylsilyl ether in the p