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Enantioselective aldol reaction mediated by chiral lithium amide bases

✍ Scribed by Masami Muraoka; Hisashi Kawasaki; Kenji Koga*

Book ID
104216372
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
137 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

Highly enantioselective aldol reaction mediated by chiral lithium amide bases was achieved between some methylketones and aldehydes .

πŸ“œ SIMILAR VOLUMES

Enantioselective aldol reactions using h
Enantioselective aldol reactions using homochiral lithium amides as non-covalently bound chiral auxiliaries.
✍ Yannick Landais; Philippe Ogay πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 330 KB

Syn and axtl aldols have been prepared from ketones and esters respectively with relatively high enantiomeric excesses, using a homochiral lithium amide possessing two coordinating sites, as non-covalently bound chiral auxiliary. The interest in HomoChiral Lithium Amides (HCLAs) as either bases in a