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Enantioselective addition of organolithium reagents to quinoline catalyzed by 1,2-diamines

✍ Scribed by Laure Cointeaux; Alexandre Alexakis

Book ID: 108283903
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 140 KB
Volume: 16
Category: Article
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2005.01.007

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The C2-symmetric bis(aziridine) ligands 1 -5 have been screened in the enantioselective addition of organolithium reagents to imines. Ligand 1 (used in stoichiometric amounts) was found to be superior in terms of chemical yield and enantioselectivity, the best result being 90\*70 yield and 89% e.e.