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Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Titanium(IV) Complexes of Diol Derivatives of d -Mannitol and the Spectroscopic Study of the Catalytic System

✍ Scribed by You, Jing-Song; Shao, Ming-Yuan; Gau, Han-Mou


Book ID
126146619
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
118 KB
Volume
19
Category
Article
ISSN
0276-7333

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Enantioselective addition of diethylzinc
✍ Sheng-Hsiang Hsieh; Han-Mou Gau πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 148 KB πŸ‘ 2 views

## Abstract An __N__‐sulfonylated β‐amino alcohol (__R__,__S__,__S__,__R__)‐**9** with four stereogenic centers is prepared. The titanium complex of **9** is an effective catalyst to induce excellent enantioselectivities for diethylzinc addition to aromatic aldehydes with ee values up to 99%. The f