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Enantiopure phosphacymantrene-2-carboxaldehyde and some of its derivatives

✍ Scribed by Bernard Deschamps; François Mathey

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
66 KB
Volume
16
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The resolution of η^5^(2‐formyl‐3,4‐dimethylphospholyl)(triphenylphosphine)‐manganesedicarbonyl 1 has been carried out by chromatography of the acetals derived from (S,S)‐1,2‐diphenylethane‐1,2‐diol. The enantiopure 2‐diphenylphosphinomethyl 4 and diphenylmethylimino 5 derivatives have been prepared from 1. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:458–460, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20130

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