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Enantiomeric specificity in the chymotrypsin-catalyzed hydrolysis of 3-carboxy-2,2,5,5-tetramethylpyrrolidino-1-oxy p-nitrophenyl ester

✍ Scribed by Flohr, Kathleen; Kaiser, E. T.


Book ID
126286115
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
273 KB
Volume
94
Category
Article
ISSN
0002-7863

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Synthesis of Enantiomerically Pure 1,5,5
✍ Markus J. Stöckli; Peter Rüedi 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 498 KB

## Abstract The irreversible inhibition of __δ__‐chymotrypsin with the enantiomerically pure, P(3)‐axially and P(3)‐equatorially X‐substituted __cis‐__ and __trans‐__configurated 2,4‐dioxa‐3‐phospha(1,5,5‐^2^H~3~)bicyclo[4.4.0]decane 3‐oxides (X=F, 2,4‐dinitrophenoxy) was monitored by ^31^P‐NMR spe