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Enantiomeric separation of glycidyl tosylate by CE: Application to the study of catalytic asymmetric epoxidation of allyl alcohol

✍ Scribed by Sonia Morante-Zarcero; Antonio L. Crego; Isabel del Hierro; Isabel Sierra; Maria Luisa Marina


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
171 KB
Volume
29
Category
Article
ISSN
0173-0835

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HPLC with polysaccharide chiral stationa
✍ Sonia Morante-Zarcero; Isabel del Hierro; Mariano Fajardo; Isabel Sierra πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 762 KB

## Abstract A simple and rapid HPLC method using a polysaccharide‐based chiral stationary phase (Chiralpak AD‐H) in polar‐organic phase mode has been developed for direct resolution of glycidyl nitrobenzoate (GNB) and 2‐methyl glycidyl nitrobenzoate (MGNB) enantiomers. ACN and methanol were used as