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Enantioface discriminating carbonylations of styrene with cationic palladium(II) catalyst precursors

✍ Scribed by Anton Aeby; Achim Gsponer; Martin Sperrle; Giambattista Consiglio


Book ID
108346623
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
121 KB
Volume
603
Category
Article
ISSN
0022-328X

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Enantioselective Carbonyl-Ene Reactions
✍ He-Kuan Luo; Lim Bee Khim; Herbert Schumann; Christina Lim; Tan Xiang Jie; Hai-Y πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 245 KB

## Abstract The palladium(II)‐BINAP‐catalyzed enantioselective carbonyl‐ene reactions between ten arylglyoxals and five alkenes were systematically investigated and demonstrated good to excellent enantioselectivities with high __ee__ values of up to 93.8 %. The results showed that both arylglyoxals