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Enantioface-differentiating enzymatic hydrolysis of ?-substituted cycloalkanone enol esters

✍ Scribed by Ohta, Hiromichi; Matsumoto, Kazutsugu; Tsutsumi, Seiji; Ihori, Tamiko


Book ID
119948782
Publisher
The Royal Society of Chemistry
Year
1989
Tongue
English
Weight
158 KB
Volume
8
Category
Article
ISSN
0022-4936

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A synthesis of (βˆ’)-deoxypodocarpic acid
✍ Takeshi Sugai; Hideaki Kakeya; Hiromichi Ohta; Mitsuo Morooka; Shigeru Ohba πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 637 KB

1~,4a~,lOa~)-(-)-l-Methoxycarbonyl-1,4a-d~ethyl-l,2,3,4,4a,9,lO, lOa-octahydrophenanthrene (deoxypodocarpic acid methyl ester l), a useful intermediate for the synthesis of various diterpenes, was synthesized from (R)-(+)-6-ethoxycarbonyl-2,6-dimethyl-l-cyclohexenyl acetate 4. The chiral starting ma