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Enantiodivergent Formal Synthesis of (+)- and (−)-Cyclophellitol from d -Xylose Based on the Latent Symmetry Concept

✍ Scribed by Kireev, Artem S.; Breithaupt, August T.; Collins, William; Nadein, Oleg N.; Kornienko, Alexander

Book ID: 126219777
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 121 KB
Volume: 70
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo048459p

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Formal Synthesis of (-)-Syringolide 1 Starting from D-Xylose Based on a Biomimetic Strategy. -A practical synthesis of (VIIa), which can be easily demethylated to the nonproteinaceous elicitor, (-)-syringolide (VIIb), is reported. The procedure utilizes the putative biosynthetic pathway by elaborat