Enantiocontrolled synthesis of (S)-3-substituted cycloalkanones from (s)-2-(p-tolylsulfinyl)-2-cycloalkenones and diorganomagnesium reagents.
✍ Scribed by Gary H. Posner; Martin Hulce
- Book ID
- 104229979
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 246 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Enantiomerically pure (S)S-(p-tolylsulfinyl)-l,4-benzoquinones with alkyl and methoxy substituents at C-2 and/or C-3 are synthesized by CAN oxidation of adequately substituted (S)S-(p-tolylsulfinyl)-l,4-dimethoxyaromatic precursors 2 or 3. These compounds were obtained by ortho-directed metallation
1997 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600 31 -094 ortho-Directed Metallation in the Regiocontrolled Synthesis of Enantiopure 2-and/or 3-Substituted (S)S-(p-Tolylsulfinyl)-1,4-benzoquinones. -It is shown that the dim