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Enantiocontrolled synthesis of C-19 tetrahydrofurans isolated from the marine alga Notheia anomala

✍ Scribed by Celina Garcı́a; Marcos A Soler; Vı́ctor S Martı́n

Book ID
104210348
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
107 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

The stereocontrolled synthesis of (2S,3S,5R)-5-[(1R)-1-hydroxy-9-decenyl]-2-pentyltetrahydro-3-furanol and (2S,3S,5S)-5-[(1S)-1-hydroxy-9-decenyl]-2-pentyltetrahydro-3-furanol, both isolated from the brown alga Notheia anomala has been achieved. The requisite configurations of the stereogenic centres were established by Sharpless asymmetric dihydroxylation and Katsuki-Sharpless asymmetric epoxidation.

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