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Enantio- and periselective nitroalkene Diels–Alder reaction

✍ Scribed by Narcis, Maurice J.; Sprague, Daniel J.; Captain, Burjor; Takenaka, Norito

Book ID
118150631
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
430 KB
Volume
10
Category
Article
ISSN
1477-0520

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Diels-Alder cycloaddittion reactions of
Diels-Alder cycloaddittion reactions of enaminothions with nitroalkenes
✍ P.D. Baruah; S. Mukherjee; M.P. Mahajan 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 738 KB

Diels-Alder cycloaddition reactions of enaminothiones (1) with nitroalkenes (5) result in very good yields (78-90%) of (2R, 3S, 4R) -6-aryl-2-ar$/furyl-3, rl-dihydro-4-dimethylamino-3-nitro-2H-thiopyrans (2) as exclusive stereoisomers. The reactions of 3-N-arylamino-1-phenylpropene-l-thiones (5) wit