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Enantio- and Diastereoselective Synthesis of syn -β-Hydroxyallylsilanes via a Chiral ( Z )-γ-Silylallylboronate

✍ Scribed by Lira, Ricardo; Roush, William R.


Book ID
126018317
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
107 KB
Volume
9
Category
Article
ISSN
1523-7060

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In the crystal, the molecule has C, symmetry (Fig. ); its conformation essentially corresponds to that which, according to MNDO calculations and NMR data, is the more stable of the two conformations in The benzene ring has an unsymmetric boat conformation, whose most striking characteristic is the m