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Enamines. III. A theoretical and photoelectron spectroscopic study of the molecular and electronic structures of aziridine enamines

✍ Scribed by Klaus Müller; Felix Previdoli

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
386 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The photoelectron (PE.) spectra of N‐vinylaziridine (1) and some methyl and ethyl substituted derivatives are discussed in the light of quantum‐chemical model calculations using the PRDDO SCF method. All aziridine enamines are found to exist as equilibrium mixtures of variable compositions, with an enamine‐type conformation (I) generally as the major and a trans‐bisected form (II) as the minor component.

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