✦ LIBER ✦
Enamines I. Vinyl Amine, a Theoretical Study of its Structure, electrostatic potential, and proton affinity
✍ Scribed by Klaus Müller; Leo D. Brown
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- German
- Weight
- 654 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The structure of vinyl amine and its reactivity towards a proton is studied by the PRDDO SCF MO method. The equilibrium structure is found to be non‐planar and barriers to inversion‐ and rotation‐dominated processes are calculated. Proton addition to vinyl amine, as a model of enamine protonation, is examined by means of electrostatic molecular potentials and C‐ versus N‐proton affinities.