Enamine phosphonates: Their use in the synthesis of α,β-ethylenic ketimines and the corresponding ketones
✍ Scribed by Mohinder S. Chattha; Adam M. Aguiar
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 102 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
As a continuation of our interest in the chemistry of phosphorus(V) enamines, 2 we wish to report the usefulness of enamine phosphonates 2 in the preparation of a,@-ethylenic ketones 2. Reported information on the preparation of compounds like 2 is rather limited.3*4'5 We have found that ;? can be pre-
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## Abstract For Abstract see ChemInform Abstract in Full Text.
C-Glycosidic phosphonates were synthesized by the addition of pyranosidic and furanosidic glycosyl radicals to ot-phosphonoacrylates which occurred with high diastereoselectivity towards the formation of n-C-glycosidic phosphonates. The products are useful substrates for the synthesis of complex hig