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Enamine Chemistry. VII. Cycloaddition Reactions of Ketene Acetals, O,N-Acetals, and N,N-Acetals

โœ Scribed by Brannock, Kent C.; Burpitt, Robert D.; Thweatt, John G.


Book ID
120208571
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
284 KB
Volume
29
Category
Article
ISSN
0022-3263

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1,3-Rearrangement of ketene-N,O-acetals
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Ketene N,O-acetals were prepared stereoselectively and submitted to a Lewis acid-mediated 1,3-rearrangement to afford C-alkylated products. The reactions proceeded in a stereoselective manner to construct a chiral quaternary carbon in high selectivity. The stereochemistry of the quaternary center wa

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