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Enamides via Long-Distance Migration of Double Bonds

✍ Scribed by Sergey A. Sergeyev; Manfred Hesse


Book ID
102254183
Publisher
John Wiley and Sons
Year
2003
Tongue
German
Weight
84 KB
Volume
86
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A new method for preparation of enamides (N‐(alken‐1‐yl) amides) by means of the ‘long‐distance' migration of the double bond in unsaturated amides in the presence of [Fe(CO)~5~] is described. The method is shown to be particularly useful for the isomerization of N‐(but‐3‐enyl)amides, while, in the case of N‐(pent‐4‐enyl) and N‐(hex‐5‐enyl) amides the mixture of products was formed and the yield of the enamide was relatively low.


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