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Emulsion polymerization: determinations of the average number of free radicals per particle and kinetic parameters by use of the particle size distribution

✍ Scribed by Show-An Chen; Kuo-Wei Wu

Book ID
107846105
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
687 KB
Volume
29
Category
Article
ISSN
0032-3861

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An unconventional amphiphile (1-[v-(4 0 -methoxy-4-biphenylyloxy)octyl]pyridinium bromide, PC8) was used as surfactant in the emulsion polymerization of styrene. At low surfactant concentration (6, 12 or 36 mmol l 21 ), curves of polymerization rate versus conversion obeyed the typical behavior char