𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Emulsion polymerisation in continuous reactor systems

✍ Scribed by Poehlein, Gary W.


Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
670 KB
Volume
14
Category
Article
ISSN
0007-1641

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Continuous reactor systems find important applications in the production of sythetic polymer latexes and increased production rates are providing additional incentives for the development of new continuous systems. The fundamental factors that should be considered in the development of continuous processes are reviewed in this paper. Particular emphasis is placed on exploring the differences between batch and continuous reactors and why these difference can lead to different latex product, even if the same recipe is employed. These factors make the task of designing continuous reactor systems based on batch research and development very difficult and risky. Thus it is recommended that small‐scale continuous reactors be employed early in a product/process development effort if that effort is likely to lead to a continuous commercial process.

The published literature on continuous emulsion polymerization reactors has been reasonably active in the past ten years. Our understanding of the chemistry and reactor modelling has been advanced but a number of areas for fruitful research remains. Some of these problems are reviewed and directions for new efforts are suggested.


πŸ“œ SIMILAR VOLUMES


Steady-state analysis of emulsion polyme
✍ Poehlein, Gary W. ;Dubner, Walter ;Lee, Hsueh-Chi πŸ“‚ Article πŸ“… 1982 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 722 KB

## Abstract A steady‐state model is presented for emulsion polymerisation in a continuous stirredtank reactor (CSTR) which is fed with a narrow particle‐size seed latex. The rather general kinetic model of Ugelstad __et al__ ^1,5^ for monodisperse particles is applied to the polymerisation among la

A novel reactor for continuous emulsion
✍ J. Meuldijk; C.J.G. van Strien; F.A.H.C. van Doormalen; D. Thoenes πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 540 KB

## It has been demonstrated earlier that a Pulsed Packed Column is a suitable reactor for continuous emulsion polymerisation of styrene. The emulsion polymerisation of viny2 acetate follows a different mechanism, which renders the process more liable to instabilities when carried out in a continuo

Stability of continuous emulsion polymer
✍ Anthony S. T. Chiang; Robert W. Thompson πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 684 KB

## Abstract The stability of continuous emulsion polymer reactors having steady feed streams was studied. Analysis of a population balance model supported the notion of micelle deprivation as the chief cause of reactor instabilities. Analysis of the moments of the distribution indicated that the sy

Emulsion copolymerisation in a flexible
✍ F.H.A.M. van den Boomen; J. Meuldijk; D. Thoenes πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 206 KB

The performance of a pulsed packed column (PPC) has been investigated for the continuous seeded emulsion copolymerisation of styrene and methyl acrylate. In the PPC, intensive radial mixing is combined with little axial mixing. Intensive local mixing provides proper emulsi"cation and high rates of h