## Abstract A new correlation of second virial coefficients of both polar and nonpolar systems is presented. It uses the PitzerβCurl correlation for nonpolar compounds, but in a modified form. The second virial coefficient of nonhydrogen bonding compounds (ketones, acetaldehyde, acetonitrile, ether
β¦ LIBER β¦
Empirical Correlation of Second Virial Coefficients for Vapor-Liquid Equilibrium Calculations
β Scribed by O'Connell, J. P.; Prausnitz, J. M.
- Book ID
- 118185468
- Publisher
- American Chemical Society
- Year
- 1967
- Weight
- 625 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0196-4305
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A new correlation has been developed for calculation of second virial coefficients of polar compounds. The new procedure uses superimposition of the square well potential function and a term accounting for the dipoltiipole interaction. Parameters for this new correlation have been determined for 13