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Empirical calculation of activation energy and transition state geometry for the cope rearrangement

✍ Scribed by Massimo Simonetta; Giorgio Favini

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
171 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

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πŸ“œ SIMILAR VOLUMES

The transition state of the claisen and
The transition state of the claisen and the cope rearrangements
✍ Kenichi Fukui; Hiroshi Fujimoto πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 French βš– 149 KB

THE double allylic (the Claisen and the Cope) rearrangementa are known to take place through an intramolecular, cyclic transtion state. The preferable form of the transition state has been demonstrated to be chairlike rather than boatlike. 1.2 Recently Hoffmann and Woodward discussed this problem fr