## Abstract Conformationally rigid systems such as xylopyranose 1,2,4‐ortho esters (**1a**) and (**1b**) and 10‐methoxy‐6‐aza‐isoadamantane (**2**), for which the identity of conformations both in the crystalline state and in solution can reasonably be assumed, provide good models for the study of
✦ LIBER ✦
Empirical analysis of vicinal proton-proton spin-spin coupling constants from the classic and modified Karplus equations in the γ-piperidone series
✍ Scribed by A. É. Aliev; A. A. Sinitsyna
- Book ID
- 112424147
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 676 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1573-9171
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## Abstract ^13^C FT single resonance spectra are obtained for two isomers of 2,6‐dichloro‐1,4‐oxathiane; one of the isomers is a racemic mixture. From a combined study of the various long‐range carbon‐proton coupling constants the conformations of both isomers could be determined. Each isomer exis