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Emission spectra and excited-state geometry of .alpha.-diketones

โœ Scribed by Evans, Ted Raymond.; Leermakers, Peter A.


Book ID
127155382
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
391 KB
Volume
89
Category
Article
ISSN
0002-7863

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The femtosecond photoisomerization of bacteriorhodopsin (bR), pumped at either 550 nm or 405 nm, was probed between 640 nm and 950 nm. The 550 nm pump spectra exhibit net gain signals peaking at > 950 nm. A transient absorption is proposed to partially cancel tbe emission. The 405 nm pump transients