✦ LIBER ✦

Emission from an excited triplet state during ECL

✍ Scribed by N. Periasamy; K.S.V. Santhanam

Book ID: 103013411
Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 391 KB
Volume: 39
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80070-x

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✦ Synopsis

The application of Marcus theory of electron transfer reactions f&r the use cf radical ion chemiluminescence of 9,10diphenylanthracene (DPA) gives a high rate constant value (LOY -10" M-' S-'1 for the formation of the second triplet state CT*). It is suggested that the near infrared emission observed during electrochemiluminescence of DPA is due to T2 -+ T'l fluorescence based on the high yield of T2 (=0.7) in the electron transfer readtion.

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