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Emerging subject for chiral separation science: Cluster boron compounds

✍ Scribed by Hana Horáková; Bohumír Grüner; Radim Vespalec


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
792 KB
Volume
23
Category
Article
ISSN
0899-0042

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Discussions are presented to get a unified picture for the boron-based and aluminum-based compounds constructed from icosahedral clusters. Twelve-atom centerless icosahedra, Al 12 and B 12 , have a covalent bonding nature, though 13-atom centered ones, Al 13 and B 13 , are metallic. Stabilization me