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Elucidation of the structure of poly(γ-benzyl-l-glutamate) nanofibers and gel networks in a helicogenic solvent

✍ Scribed by Ansgar Niehoff, Alexandre Mantion, Richard McAloney…

Book ID
120795484
Publisher
Springer
Year
2012
Weight
677 KB
Volume
291
Category
Article
ISSN
0340-255X

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The molecular-weight dependence of the rms radius of gyration »R 2 g … 1/2 of poly(gbenzyl L-glutamate ) (PBLG) in helicogenic solvents shows negative and positive deviations from expectations for an intact and rigid a-helix in the higher and lower molecular-weight ranges, respectively. In order to

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## Abstract The storage and loss shear moduli, __G__, and __G__˝, have been measured for solutions of three samples of poly‐γ‐benzyl‐L‐glutamate with molecular weights from 16 to 57 × 10^4^, by use of the Birnboim‐Schrag multiple‐lumped resonator. The frequency range was 106 to 6060 H~z~, the conce

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The gelation and gel-melting phenomena in semidilute isotropic solutions of poly(y-benzyl-L-glutamate) (PBLG) in benzyl alcohol were studied by small-angle neutron scattering measurements, using a deuterated solvent, and by cryotransmission electron microscopy. The reversible gels are formed when th