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Elucidating Mechanistic Details of Catalytic Reactions Utilizing Gas Phase Clusters

โœ Scribed by M. L. Kimble; D. R. Justes; N. A. Moore; Jr. Castleman; A. W.


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Gas-phase reactions of XH3+ (X = C, Si,
โœ Paola Antoniotti; Lorenza Operti; Roberto Rabezzana; Francesca Turco; Cristina Z ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 507 KB

## Abstract The gasโ€phase reaction of CH~3~^+^ with NF~3~ was investigated by ion trap mass spectrometry (ITMS). The observed products include NF~2~^+^ and CH~2~F^+^. Under the same experimental conditions, SiH~3~^+^ reacts with NF~3~ and forms up to six ionic products, namely (in order of decreasi