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Elongation cutoff technique armed with quantum fast multipole method for linear scaling

✍ Scribed by Jacek Korchowiec; Jakub Lewandowski; Marcin Makowski; Feng Long Gu; Yuriko Aoki


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
505 KB
Volume
30
Category
Article
ISSN
0192-8651

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✦ Synopsis


Abstract

A linear‐scaling implementation of the elongation cutoff technique (ELG/C) that speeds up Hartree‐Fock (HF) self‐consistent field calculations is presented. The cutoff method avoids the known bottleneck of the conventional HF scheme, that is, diagonalization, because it operates within the low dimension subspace of the whole atomic orbital space. The efficiency of ELG/C is illustrated for two model systems. The obtained results indicate that the ELG/C is a very efficient sparse matrix algebra scheme. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2009