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Elisapterosins D and E: complex polycyclic diterpenes of the rare elisapterane class of natural products from the Caribbean sea whip Pseudopterogorgia elisabethae (Bayer)

✍ Scribed by Yan-Ping Shi; Ileana I. Rodrı́guez; Abimael D. Rodrı́guez


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
98 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


From the hexane extracts of a Colombian specimen of Pseudopterogorgia elisabethae (Bayer) we have isolated elisapterosin D (2) and elisapterosin E (3), two structurally complex polycyclic diterpenes based on the rare elisapterane carbon skeleton. The structures of these scanty compounds were elucidated after interpretation of their combined spectroscopic data and NMR spectral comparisons with known elisapterane models.


📜 SIMILAR VOLUMES


Ileabethin: isolation and structure of a
✍ Abimael D. Rodrı́guez; Ileana I. Rodrı́guez 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 103 KB

A recent chemical investigation of the hexane extract of a Colombian specimen of Pseudopterogorgia elisabethae (Bayer) has led to the isolation of ileabethin (1). This novel diterpene possesses a previously undescribed carbon skeleton which appears to be biosynthetically related to the serrulatane (