✦ LIBER ✦

Elimination Voltammetry of Miniaturized Mercury Drop Electrodes

✍ Scribed by Libuse Trnkova; Ladislav Novotny; Nuria Serrano; Katerina Klosova; Petra Polaskova

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 292 KB
Volume: 22
Category: Article
ISSN: 1040-0397
DOI: 10.1002/elan.201000120

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Elimination voltammetry with linear scan (EVLS) in connection with renewed mini‐ drop mercury electrodes provides valuable information about the character and kinetics of processes at electrode/electrolyte interfaces. Based on the experiment related to the hydrogen evolution, it is presented that the EVLS is more sensitive than other voltammetric methods. Using miniaturized mercury electrodes, the EVLS is capable of detecting the effect of spherical diffusion associated with both the scan rates and the size of an electrode drop.

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