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Elimination reactions of ions in the gas phase–I: Elimination of water and acetic acid in epimeric borneols and bornylacetates

✍ Scribed by R. Robbiani; J. Seibl

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
557 KB
Volume
7
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Loss of water and acetic acid in the epimeric bornyl alcohols and acetates are shown to be analogous processes by specific ^2^H‐labelling. Among several competing mechanisms cis‐1,2‐elimination is the most important. Mctastable ion characteristics of this specific process exhibit some unusual features and its product is shown to have a different structure from that produced by the competing reactions.

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