Elimination and Metathetical Reactions and the Electronic Theory of Rearrangements
โ Scribed by Hauser, Charles R.
- Book ID
- 126191857
- Publisher
- American Chemical Society
- Year
- 1940
- Tongue
- English
- Weight
- 853 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
In the foregoing papers (2,3), it was reported that dialkylaminoalkyl S-alkyl xanthntes thermally rearrange to dialkylaminoalkyl alkyl dithiolcarbonates with or without shift of the dialkylamino group. The general feature of the rearrangement is that .it requires antiparallel coplanarity of the xan
A metathetical reaction between carbon tetrachloride and toluene to give benzyl chloride and chloroform occurs at temperatures above 200ยฐC (k = 4.8 X 1Olo e-82,m/RT cc mole-'sec-'). The reaction does not involve free radicals, as is shown by the kinetic behavior of the system, by the lack of effect