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Elimination and Metathetical Reactions and the Electronic Theory of Rearrangements

โœ Scribed by Hauser, Charles R.


Book ID
126191857
Publisher
American Chemical Society
Year
1940
Tongue
English
Weight
853 KB
Volume
62
Category
Article
ISSN
0002-7863

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Rearrangement and trans-elimination agai
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A metathetical reaction between carbon tetrachloride and toluene to give benzyl chloride and chloroform occurs at temperatures above 200ยฐC (k = 4.8 X 1Olo e-82,m/RT cc mole-'sec-'). The reaction does not involve free radicals, as is shown by the kinetic behavior of the system, by the lack of effect