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Elevated temperature–extended column length conventional liquid chromatography to increase peak capacity for the analysis of tryptic digests

✍ Scribed by Pat Sandra; Gerd Vanhoenacker


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
332 KB
Volume
30
Category
Article
ISSN
1615-9306

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✦ Synopsis


Abstract

High efficiency separations (200 000 plates) were obtained on conventional LC equipment by coupling 8×25 cm×2.1 (or 4.6) mm id×5 μm d~p~ ODS columns (total length 2 m) and operation at 60°C using a dedicated LC oven. The peak capacity in this 1‐D set‐up was 900 for the separation of human serum tryptic peptides analyzed after depletion of six highly abundant proteins. The chromatographic performance of an elevated temperature–extended column length conventional LC is highlighted.