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Elementary Steps in Gold Catalysis: The Significance of gem-Diauration

✍ Scribed by Ing. Günter Seidel; Prof. Christian W. Lehmann; Prof. Alois Fürstner

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
423 KB
Volume
49
Category
Article
ISSN
0044-8249

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Elementary Steps of Gold Catalysis: NMR
Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a “Gold Carbenoid”
✍ Günter Seidel; Richard Mynott; Alois Fürstner 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

## Abstract **Was bist Du?** Die metallinduzierte Ringöffnung 3,3‐disubstituierter Cyclopropene liefert bekanntlich Carbene; doch bei der Verwendung von Au^I^ in dieser Reaktion erhält man ein reaktives Intermediat mit deutlich kationischem Charakter. Diese Beobachtung hat große Konsequenzen für di

Elementary Steps of Gold Catalysis: NMR
Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a “Gold Carbenoid”
✍ Günter Seidel; Richard Mynott; Alois Fürstner 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

## Abstract **What are you?** Even though the metal‐induced ring opening of 3,3‐disubstituted cyclopropenes is known to serve as a genuine carbene generator, the use of Au^I^ in this reaction leads to a reactive intermediate with highly cationic character. This result has important implications for