✦ LIBER ✦
Elektrocyclischer Ringschluss als Nebenreaktion bei einer Wolff-Kishner-Reduktion. Über Steroide, 227. Mitteilung
✍ Scribed by H. Kaufmann; P. Wieland; J. Kalvoda
- Book ID
- 102855275
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- German
- Weight
- 526 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
A side reaction occurring in the Wolff‐Kishner reduction of certain acetylenic aldehydes (as e.g. 2 or 10) is shown to be a synchronous thermal process. The mechanism of this reaction is discussed in terms of the rules of the conservation of orbital symmetry.